China has a vast area of mountains that are of great research interest. Chongqing is a typical mountain city in China. In urban construction, a mountain is not only an important limiting condition for urban development, but also an important condition for shaping the urban form. The area from the Yangtze River to the eastern ridge line of Nan Mountain in Nanan District is strongly representative of mountain cities with a complex landform, fragile ecological environment and a long history and culture. In recent years, the construction and optimization of this area are increasingly closely related to the landscape environment. However, due to the special environments of mountain cities, altitude and landform conditions become the key influencing conditions for further development of the cities. Therefore, this paper takes this region as an example, focuses on remote sensing and field measurement data, combines government data with that from scholarly research, and conducts relevant exploration through GIS, ENVI and some chart processing software. At first, from the perspective of the landscape gradient and urban construction, the characteristics of the urban landscape gradient are sorted out, and the developmental status of each urban area is analyzed. Then, the coupling relationships between the landscape features of each gradient and each urban area are analyzed. Finally, based on the analysis results, three major optimization measures are proposed to maintain ecological harmony in the mountainous area, reconstruct the mountain characteristic culture, and create unique mountain aesthetics, all with the hope of providing some guidance for the future development of the study area and similar mountain cities.