The Solvent-initiated Photolysis of Dichloro(2,2′-bipyridine)platinum(II) in Chloroform¶

Sharon Whang; Toño Estrada; Patrick E. Hoggard

doi:10.1562/2003-12-05-RA.1

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Sharon Whang,¹ Toño Estrada,¹ Patrick E. Hoggard^1,*

¹Department of Chemistry, Santa Clara University, Santa Clara, CA

^**To whom correspondence should be addressed: Department of Chemistry, Santa Clara University, Santa Clara, CA 95053, USA. Fax: 1-408-554-7811; phoggard@scu.edu

Abstract

Under 254 nm irradiation, [Pt(bpy)Cl₂] is converted to [Pt(bpy)Cl₄] in a solvent-initiated process. The reaction is very nearly zero order throughout. The rate decreases slightly with increasing starting concentration. These characteristics can be rationalized by a rate law of the form af_S, where f_S is the fraction of light absorbed by chloroform. The species that reacts with [Pt(bpy)Cl₂] is believed to be CCl₃OO.

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Sharon Whang, Toño Estrada, and Patrick E. Hoggard "The Solvent-initiated Photolysis of Dichloro(2,2′-bipyridine)platinum(II) in Chloroform," Photochemistry and Photobiology 79(4), 356-359, (1 April 2004). https://doi.org/10.1562/2003-12-05-RA.1

Received: 3 December 2003; Accepted: 1 January 2004; Published: 1 April 2004

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