Payments for ecosystem services (PES) are one kind of important tool for environmental protection, and have been widely studied by international scholars and conservationists. Based various definitions of PES from recent articles, we have outlined four principles for PES: parity, measurability, additionality and conditionality, and then have used these principles to develop a formula to calculate a standard for PES. Finding a way to use PES to achieve a win-win relationship between economic growth and environmental protection in the Beijing-Tianjin-Hebei Region (BTHR) is a key task for Chinese government. Synergetic development of BTHR has become a national strategy, like The Belt and Road Initiative. This article employed the formula we developed to calculate the net horizontal PES amounts that each provincial government within BTHR should pay. Our findings show that Beijing should have paid 10.44×10⁹ Yuan (0.4% of Beijing's GRP) and Tianjin 16.56×10⁹ Yuan (0.93% of Tianjin's GRP) to Hebei in 2016.