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24 June 2022 Extracting the Critical Points of Formaldehyde (HCHO) Emission Model in Hot Desert Climate
Chuloh Jung, Naglaa Sami Abdelaziz Mahmoud
Author Affiliations +
Abstract

Indoor air pollutants have various emission patterns and are influenced by indoor microclimate, the physical properties of building materials, and types of chemical substances. The difference in these emission patterns affects the prediction via simulation. This paper aims to extract factors that have an important influence on selecting empirical models by examining the emission pattern of formaldehyde (HCHO) from building materials. As a methodology, Small Chamber Pollutant Emission Test was used for six different flooring and wallpaper specimens, and HCHO was sampled and analyzed using HPLC (High-Performance Liquid Chromatography). The result showed that the higher the linear relationship between emission intensity and time, the more appropriate the first-order reduction model, such as flooring-A (R2 = .99), flooring-B (R2 = .94), wallpaper-A (R2 = .99), and wallpaper-C (R2 = .98). The emission pattern of HCHO in building materials is classified into three types: In type I (R2 = .00–.11), the emission of chemical substances reaches the maximum after the start of the experiment and decreases relatively rapidly. Type II (R2 =.00–.41), the emission pattern having the shape of a vertex with a refined concentration ascending and a gentle descending and is a type in which the suitability is significantly high in the concentration descending section, and Type III (R2 = .33–.60), which shows a mild linear increase and decreases trend in the ascending and concentration dropping sections. It is a type that indicates the suitability with the predicted value in a meaningful way in the entire area. Even though many previous studies focused on the concentration descending section in different materials (R2 = .51–.95), it was confirmed that the emission characteristics in the initial concentration ascending section are also critical points for simulation model selection since R2 of ascending section of Type II (.67–.70) and Type III (.77–.93) turned out statistically meaningful except Type I (.02–.25).

Introduction

The generation of indoor air pollutants in building materials is influenced by many factors such as indoor microclimate, the physical properties of building materials and types of chemical substances, and the external environment. It has a variety of emission patterns (Awad & Jung, 2021; D’Ovidio et al., 2021; Jung & Awad, 2021; Kubečková et al., 2020). The emission pattern refers to the tendency to change due to the increase and decrease of chemical substances’ emissions in the building material (Peng et al., 2017; Piasecki et al., 2018). This pattern has various shapes due to the difference in the initial emission amount, the maximum emission amount, the time to reach the peak, and the decreasing tendency (Liang & Yang, 2013). The difference in these emission patterns affects the prediction through simulation (Xing et al., 2020).

The use of simulation to predict chemical concentration is beneficial in saving time and money. It has meaning when the prediction through simulation becomes more consistent with the actual value (Palmisani et al., 2020; Rosen & Kishawy, 2012). The prediction of chemical substances is based on numerical and empirical models, and empirical models using measured values are beneficial based on their convenience (Cho & Choi, 2014; Peng et al., 2017). However, in the case of the practical model, only limited parameters are substituted, so it has limitations in predicting based on the diversity of the emission pattern (Breen et al., 2014).

Several previous researchers have reported the applicability of different empirical models based on the emission characteristics of various building materials such as paints, adhesives, and wood (Böhm et al., 2012; Kozicki & Guzik, 2021; Tudor et al., 2020; Wi et al., 2020). However, this has the aspect that there is a difference in the emission pattern depending on the content of chemical substances inside the building material (Khoshnava et al., 2020). Selecting the first order and double exponential decay models according to the type of building material involves risks in choosing an appropriate model (Gładyszewska-Fiedoruk et al., 2019; Huang et al., 2016). Therefore, it will be beneficial to extract and utilize factors for selecting a suitable empirical model based on the emission pattern that exists according to the characteristics of the material rather than the classification by the type of building material (Marzocca et al., 2017; Tran et al., 2020).

When estimating the emission intensity or indoor concentration of chemical substances, a numerical model based on the mass transfer equation and an empirical model based on actual values (Piasecki & Kostyrko, 2020). The more easily applicable is the practical model (Ahn et al., 2017). The first-order reduction models and the double exponential decay model (He et al., 2019; Liu et al., 2015). The first-order decay model, proposed by Gunschera et al. (2013), is suitable for explaining the emission characteristics of chemical substances in which the evaporation process is dominant in building materials (equation (1)).

(1)

10.1177_11786221221105082-eq1.tif

E(t) = Amount generated per unit area at time t (mg/m2h)

E0 = Amount generated per unit area at t = 0 (mg/m2h)

k = first-order reduction constant (h−1)

t = time (h)

The double exponential decay model, proposed by de Gennaro et al. (2015), explains the emission characteristics of building materials in which internal emission is dominant (equation (2)).

(2)

10.1177_11786221221105082-eq2.tif

E1 = Amount of occurrence at t = 0 in a rapidly decreasing process (mg/m2h)

k1 = Decrease constant for rapid decay (h−1)

E2 = The amount of occurrence at t = 0 in a slow-decreasing process (mg/m2h)

K2 = Decrease constant for slow decay (h−1)

t = time (h)

The above empirical model equation was made based on the characteristics of the decreasing period rather than the application to the initial period of increasing concentration (Mocho et al., 2017).

Conformity verification by empirical models has been reported by many researchers (Ai et al., 2015; Jomehzadeh et al., 2017). They apply the model formula based on building materials, mainly considered diffusion-dominated and evaporation-dominated by the characteristics of the reduction section in the concentration change over time (Geng et al., 2017). Missia et al. (2010) reported that hazardous chemical substances were measured through small chamber experiments on wood and carpet, such as PB and plywood. As a result of prediction through a double exponential decay model, it showed high suitability in all materials. Salem et al. (2012) reported a higher fit in the double exponential decay model than the first-order reduction model due to predicting the HCHO concentration in new houses using measured data from PB and MDF. The above studies report the suitability of the double exponential decay model using wood products (Xiong et al., 2019). In applying the empirical model, the emission characteristics of the concentration ascending section are not considered, and the features of the emission intensity descending area after the maximum emission intensity are identified (Liu et al., 2015).

Wang et al. (2021) showed a difference in the initial emission amount and different radiation patterns. It was reported that the emission pattern of the specimen with a low initial emission amount, even though it was a wood product, was slightly reduced or showed an equilibrium state, indicating that the first-order reduction model was highly suitable (Hérault et al., 2010). It was also reported that even in the case of the same wood products, there was a difference in the emission pattern due to the difference in the initial emission amount, and there was a difference in the suitability of the model applied to it (Böhm et al., 2012).

Previous studies have reported a critical point in selecting an empirical model based on the emission pattern, and it is essential to determine an appropriate practical model based on this (Mu et al., 2020). It is judged that it will be helpful to increase the suitability of the model application to find factors that have an important influence on the model decision by further subdividing the emission pattern (Nogueira et al., 2017).

This study aims to derive factors that influence selecting empirical models, such as the primary reduction model and the double exponential decay model, by examining the emission pattern of formaldehyde (HCHO) emitted from building materials.

Materials and Methods

Construction materials overview

The building materials used in this study were the flooring and wallpaper used the most as interior finishing materials (Arar & Jung, 2021; Jung et al., 2021). Table 1 is an overview of experimental building materials. On the premise that the emission pattern differs depending on the chemical substances’ content, different production dates were selected, or the number of elapsed days was selected differently by other testing dates for the same material (Sarbu & Sebarchievici, 2013).

Table 1.

Outline of Test Pieces.

10.1177_11786221221105082-table1.tif

Flooring-A and flooring-B are from the same manufacturer, while flooring-C is from a different manufacturer. Wallpaper-A and wallpaper-B are also from the same manufacturer, but wallpaper-C is from another manufacturer.

As for the storage form after the production of the above materials, the wallpaper was sealed in plastic, the flooring was packaged in a general paper box, and the materials stored at room temperature in the material warehouse of each producer were used.

Small chamber pollutant emission test

According to ISO (2020) (the International Organization for Standardization) a small chamber system 16,000, test pieces are prepared with 160 mm × 160 mm to analyze each specimen’s hazardous chemical generation. HCHO was collected using an LpDNPH S10L cartridge (Supelco Inc., U.S) to contain carbonyl compounds (Williams et al., 2019). To remove the interference caused by Ozone (O3), the O3 scrubber was connected in front of the LpDNPH S10L cartridge, and the sample was collected by clicking it on a flow sampling pump (Tucker, 2014). At this time, 7.0 l of collected air in the chamber was collected at 167 ml/min, and the collected samples were stored in a cool and dark place until extraction (Even et al., 2021). For the extraction of the analytical model, the DNPH-carbonyl derivative formed by reacting with DNPH was extracted with 5 ml of HPLC grade acetonitrile, and analysis was performed immediately (Zhang et al., 2014). The examination for HCHO was performed using HPLC (High-Performance Liquid Chromatography, Shimadzu).

Since the UAE is located in a hot arid desert and the residents spend 90% of their time indoors with air-conditioning due to scorching summer and no apparent differences between seasons, The environmental conditions in the chamber were maintained at a temperature of 25°C, relative humidity of 50%. The number of ventilation at 0.5 times/h to simulate the indoor condition with central air-condition in Dubai, UAE. The sample loading rate was 2.2 m2/m3, the exposed surface area of the test piece was 0.044 m2, and the emission intensity was calculated as shown in equation (3) below (Murata et al., 2013).

(3)

10.1177_11786221221105082-eq3.tif

SERa = Emission amount per unit area of specimen (mg/m2h)

Ct = Contaminant concentration in the small chamber at time t (mg/m3)

t = Elapsed time after the start of the test

A = surface area of the specimen (m2)

Q = Flow rate in small chamber (m3/h)

n = Number of ventilation (times/h)

V = Volume of small chamber (m3)

L = Sample load factor (m2/m3)

q = Flow rate per unit area (m3/m2h)

Emission intensity prediction from building materials

The parameters for the application of the first-order reduction model and the double exponential decay model were calculated as shown in Table 2 below using the initial emission intensity, the first reduction constant, and the second reduction steady of each specimen figured through the small chamber emission experiment, and this was used to predict the emission intensity (Hult et al., 2015; Liang et al., 2016; Seo et al., 2013).

Table 2.

Parameters for Prediction for Each Specimen.

10.1177_11786221221105082-table2.tif

Results

Experimental results and analysis

An important point to be dealt with through this experiment is to identify the characteristics of critical issues that indicate the difference in shape in the graph of the emission pattern (Lim et al., 2014). The variables applied to calculating the predicted value through the empirical model are the initial emission intensity, the maximum emission intensity, and the reduction constant (Nogueira et al., 2017). As for the reduction constant, one is applied in the case of a linear reduction model and two in the case of a double exponential decay model (He et al., 2019). In particular, when using the double exponential decay model, it is essential to determine the breakpoint of the change in the descending section (Chi et al., 2016). In the simulation through the empirical model, the researcher has to calculate and input the information of each breakpoint, so the calculation of clear measurement values for these critical points enables valid prediction (Bourdin et al., 2014).

In addition, for each specimen, a concentration change trend line was calculated based on the measurement point to derive an emission pattern. This is based on the dissipation pattern of general building materials, which initially rises for a certain period and then decreases (Liu et al., 2015).

In this section, it is essential to improve the suitability of the predictive model to derive a distinguishing factor by examining the initial emission intensity, which is a crucial point in determining the emission pattern, the shape of the vertex indicating the maximum value, the appearance time of the vertex, and the reduction period that determines the subsequent decrease pattern (Mu et al., 2020). Regression analysis was performed on the fit between the measured and predicted values to analyze the degree of explanation of the linear relationship between predicted and actual values (Shalbafan & Thoemen, 2020).

Analysis and characterization of important breakpoints in emission patterns

Flooring

The initial emission intensity refers to the emission intensity within 24 hours after the specimen is put into a small chamber (An et al., 2010). According to Figure 1, the emission intensity at the first measurement point 1 hour after the material was put into the chamber showed a difference by material. Flooring-A showed the lowest emission intensity at 1.31 µg/m2h but showed a high rate of increase after that. At 24 hours, all materials exhibited emission intensity levels of 11.19 to 13.14 µg/m2h. After that, there is a difference in the form of emission according to the characteristics of each material.

Figure 1.

Emission pattern of HCHO over time for each flooring material.

10.1177_11786221221105082-fig1.tif

In the case of Flooring-C, it showed the lowest emission intensity within about 100 hours in the initial period. It decreased slightly after that, leading to the lowest cumulative emission amount, as shown in Figure 2. Flooring-A initially showed the lowest emission intensity, increasing rapidly after about 100 hours, offering the highest cumulative emission amount.

Figure 2.

Cumulative emission of HCHO over time for each flooring material.

10.1177_11786221221105082-fig2.tif

It is difficult to predict the degree of emission pattern of alternative materials based on the initial emission intensity alone (Rackes & Waring, 2016). To effectively use the initial emission intensity, it is understood that a pre-treatment process for the experiment after inducing the emission at a temperature close to the experimental temperature for a certain period is necessary (Robertson et al., 2012). Therefore, if the material storage process is not straightforward, conducting the chamber experiment is desirable after undergoing a pre-treatment process for at least 24 hours.

The shape of the graph of the emission pattern changes according to the form of the vertex. It is a significant time because it is usually classified into an increasing section and a decreasing section of chemical substances. As for the shape of the vertices, in the case of Flooring-A and B, the shape of the bell is taken, and in the case of Flooring-C, the form of the vertex is a gentle curve. In this study, flooring-C with relatively low cumulative emission had a soft curve shape, and flooring-A and B with high cumulative emission showed a bell-shaped vertex. Flooring-A showed the most distinct diffusion pattern of increasing and decreasing concentration.

Figure 3 shows the degree of the linear relationship between the emission intensity and the elapsed time from 1 to 48 hours after material input, based on the vertex of each flooring material. In the case of flooring-A and flooring-B, the bell-shaped vertex was derived, R2, which indicates the degree of the linear relationship between time elapsed and emission intensity, was .94 or more, showing a solid linear relationship. In the case of flooring-C, R2 was .44, indicating a relatively low degree of a linear relationship.

Figure 3.

Linear correlation with HCHO in the concentration ascending section for each flooring material.

10.1177_11786221221105082-fig3.tif

The section where the emission intensity decreases from the vertex shows a more complex shape. In applying the empirical model, in the case of the first-order reduction model, it is assumed that the reduction trend decreases linearly in the concentration-falling section. The double exponential decay model is a case where it is considered that this part is divided into two parts, an area in which the decay occurs rapidly and a section in which the reduction occurs slowly. Therefore, looking at the degree of relationship that can infer these linear relationships, in the case of flooring-C, R2 was .88, and that of flooring-B was .89. Flooring-A showed a slightly weakened linearity of .76.

In the case of flooring-A, which significantly deviates from the linear relationship in the concentration drop section, there are two inflection points in the reduction pattern, as shown in Figure 4. It is judged that the double exponential decay model is more suitable, and it is inferred that the first-order reduction model is more ideal for flooring-C and flooring-B.

Figure 4.

Linear correlation with HCHO in the concentration descending section for each flooring material.

10.1177_11786221221105082-fig4.tif

Wallpaper

In the case of wallpaper, the initial emission intensity at the time point 1 hour after injecting the sample into the chamber was in the range of 0.75 to 1.48 µg/m2h for each wallpaper, showing a similar level. After 24 hours were completed, the difference in emission intensity for each wallpaper was demonstrated.

As shown in Figure 5. Wallpaper-C exhibited a maximum release intensity of 21.90 µg/m2h at 144 hours, and Wallpaper-A exhibited a maximum release intensity of 10.26 µg/m2h at 24 hours. After the peak, there was a rapid decrease followed by a gradual decrease. Wallpaper-B showed a tendency to slightly increase and decrease without significant change in concentration in almost all sections.

Figure 5.

Emission pattern of HCHO over time for each wallpaper.

10.1177_11786221221105082-fig5.tif

The following is an analysis of the shape of the vertices in the graph of the diffusion pattern. Wallpaper-A showed the highest release intensity when 24 hours had elapsed, and in the case of Wallpaper-C, when 144 hours had elapsed after the sample was added. This corresponds to the vertex of the bell on the graph. It can be seen that wallpaper-A and wallpaper-C show a difference in the time points representing the peaks of the highest emission intensity. As shown in Figure 6, it can be confirmed that the peak appearance time is delayed in the case of wallpaper-C, which has the most significant cumulative emission. A graph of a typical bell-shaped dissipation pattern showing a continuous decrease after a constant increase is shown. However, in the case of Wallpaper-B, it was confirmed that the diffusion pattern showed a gentle curve rather than a vertex, and the cumulative emission amount was also the least.

Figure 6.

Cumulative emission of HCHO over time for each wallpaper.

10.1177_11786221221105082-fig6.tif

As shown in Figure 7, in the linear relationship between the time elapsed to the peak and the emission intensity in the concentration rise section, wallpaper-A and wallpaper-C, which have bell-shaped vertices, have a strong linear relationship with R2 .98 or more. Wallpaper-B was .61, indicating a weak linear relationship. In addition, in the case of wallpaper-B, R2 was .91, showing an excellent linear relationship in the concentration decreasing section. In wallpaper-A and wallpaper-C, R2 was less than .78, indicating a weak linear relationship.

Figure 7.

Linear correlation with HCHO in the concentration ascending section for each wallpaper.

10.1177_11786221221105082-fig7.tif

As shown in Figure 8, there is an inflection of the measurement points deviating from the line graph in the case of wallpaper-A and wallpaper-C. In this case, it is judged that applying the double exponential decay model is reasonable. When it has a bell-shaped vertex in the diffusion pattern and a clear concentration reduction pattern is secured, it is predicted that the double exponential decay model will be helpful, and the first-order reduction model is suitable for showing a strong linear relationship in the concentration reduction section.

Figure 8.

Linear correlation with HCHO in the concentration descending section for each wallpaper.

10.1177_11786221221105082-fig8.tif

Emission intensity prediction result

The emission pattern was classified into three types by comparing the way for each building material obtained in this experiment with the results predicted by each model (Jiang et al., 2017; Zhou et al., 2016). In addition, regression analysis analyzed the fit between the measured and indicated values, and critical points’ characteristics were derived for selecting a suitable model for each type (Li et al., 2019).

Type I emission pattern

Type I is an emission pattern that shows a low fit between the measured and predicted values in the entire interval. In particular, it offers a difference between the expected value and the actual value for the peak emission intensity. The measured value has a characteristic that significantly deviates from the prediction pattern of the two models (Frihart et al., 2020). Wallpaper-C, which was shown to have a relatively high HCHO, corresponds to this type.

Figure 9 shows the emission patterns of the predicted and measured values of HCHO using the linear and double exponential decay models for wallpaper-C. There is a big difference in the emission pattern between the predicted and measured values according to the difference in the time point showing the highest emission intensity.

Figure 9.

Emission pattern of HCHO based on the measured and predicted values of wallpaper-C.

10.1177_11786221221105082-fig9.tif

For this type, as shown in Table 3, R2, which shows the explanatory power between the predicted values for the measured values of the entire section, was .11 in the first-order reduction model and .00 in the double exponential decay model, indicating no or shallow level of explanatory power.

Table 3.

Regression Analysis of Measured Values for Each Section and Predicted Values for Each Model.

10.1177_11786221221105082-table3.tif

The explanatory power R2 of the predicted value in the concentration ascending section was .25 for the first-order reduction model and .19 for the double exponential decay model. This was meaningless at a significant probability of .1 or less. In the concentration descent section, R2 was .51 in the first-order reduction model and .72 in the double-exponential reduction model, indicating good explanatory power. There was no sign of a significant probability of .1 or less.

Type II Emission pattern

In Type II, the emission pattern of the measured values in the entire section is close to the emission pattern of the predicted values by the two models. Consistency is high in the descending concentration area, and the peak emission intensity appears later than the expected value (Wei et al., 2013). Figure 10 shows the emission pattern of the HCHO predicted value and the actual value predicted using the first-order and double exponential decay models for flooring-A.

Figure 10.

Emission pattern of HCHO based on the measured and predicted values of flooring-A.

10.1177_11786221221105082-fig10.tif

As shown in Table 3, R2, the degree of explanation of the predicted values for the actual values in the entire interval was .00 for the first-order reduction model and .13 for the double exponential decay model.

In addition, in the concentration ascending section based on the vertex, R2 was found to be .02 for the first-order decay model and .15 for the double exponential decay model.

In the concentration descending section, the first-order decay model was .56, and the double exponential decay model was .72, indicating a relatively good degree of explanation in the concentration descending section. In particular, the explanatory power in the concentration-descent area showed a significant result at a substantial probability of .1 or less. Therefore, in the case of flooring-A, the low suitability of the entire section is pointed out as the cause of the low linear explanatory power in the concentration ascending section.

Wallpaper-A and flooring-B are also divided into the same emission patterns. In the case of wallpaper-A (Figure 11), it can be seen that the emission pattern according to the measured values shows a slight increase in the maximum emission intensity and a gradual decrease in the concentration. According to Table 3, in the case of wallpaper-A, R2, which shows the explanatory power of the predicted values for the actual values in the entire section, is .41 for the first-order reduction model and .15 for the double exponential decay model. The first-order reduction model showed a relatively higher fit, and in particular, a significant result was established with a substantial probability of .05 or less.

Figure 11.

Emission pattern of HCHO based on the measured and predicted values of wallpaper-A.

10.1177_11786221221105082-fig11.tif

The degree of explanatory value R2 of the predicted value in the concentration ascending section was .67 for the first-order decay and .70 for the double exponential decay model, but this wasn’t very meaningful at a significant probability of .1 or less. On the other hand, in the concentration descending section, the first-order reduction model showed a significant result at the significance level of .05 or less with an R2 of .72. In the double exponential decay model, R2 was .53, and the significance probability was less than .05.

The flooring-B (Figure 12) showed relatively low explanatory power in the entire section and was statistically insignificant. R2 was .23 for the first-order decay model in the concentration ascending section and .20 for the double exponential decay model. These did not show any significant results at a substantial probability of .1 or less.

Figure 12.

Emission pattern of HCHO based on the measured and predicted values of flooring-B.

10.1177_11786221221105082-fig12.tif

However, it showed a very high explanatory value in the concentration descending section. In the first-order decay model, R2 was .92, and in the double exponential decay model, R2 was .95.

Type II showed extreme suitability in the concentration descending section and a relatively good fit in the ascending section. In addition, it can be seen that the suitability of the predicted values and the actual values for all measurement points improved compared to Type I as the suitability for the concentration ascending section improved.

Type III emission pattern

Type III is an emission pattern that does not show the shape of distinct vertices in the concentration ascending section. It offers a solid linear relationship between the concentration ascending section and the decrease section (Blondel & Plaisance, 2011).

Flooring-C (Figure 13) and wallpaper-B (Figure 14) exhibit an emission pattern that does not have a distinct apex. At the point of declination, the distinction between fast and slow decreases does not occur clearly. Therefore, it is judged that it is unnecessary to distinguish between the first-order decay model and the double exponential reduction model.

Figure 13.

Emission pattern of HCHO based on the measured and predicted values of flooring-C.

10.1177_11786221221105082-fig13.tif

Figure 14.

Emission pattern of HCHO based on the measured and predicted values of wallpaper-B.

10.1177_11786221221105082-fig14.tif

As shown in Table 3, in the case of flooring-C, R2, which indicates the degree of the linear explanatory value of the predicted values for the entire section, was .36 for the first-order decay model and .33 for the double exponential reduction model. This showed a significant result at a substantial probability of .05 or less.

In addition, in the concentration ascending section, R2 was .93 in both the first-order reduction model and the double-exponential reduction model, indicating a high degree of explanation distinguished from other specimens. This showed a significant result at a substantial probability of .01 or less. An excellent explanatory degree was established in the concentration descending section, and essential development was demonstrated at the significance probability level of .05.

In wallpaper-B, the first-order decay model had an R2 of .58 and the double exponential reduction model of .60, indicating a good fit. A significant result was shown with a substantial probability of .01 or less. In addition, the first order and double exponential decay models showed a relatively good fit to the same degree and statistically significant results in the concentration descending section.

In Type III, the explanatory power of the predicted values for the actual values increased in the entire section, and statistically significant results were obtained. In particular, it is judged that the high suitability in the ascending concentration section had a considerable influence.

Discussion

In this study, when the peak appeared late in the emission pattern of HCHO and showed a general characteristic of gently decreasing (Type I and II emission pattern), no significant results were demonstrated in conformity with the predicted values by the empirical model. This is because in the case of building materials with a high content of HCHO, the peak appears later than in the case of the generally expected emission pattern (Salthammer, 2019).

It is judged that it is essential to secure sufficient prediction time for the entire process in the emission pattern in which the appearance of vertices is relatively late (D’Amico et al., 2020). In the case of the emission pattern of HCHO, it was confirmed that it is a prerequisite for applying the empirical model to secure a sufficient period of reduction after the peak and to position the ultra-high rise early in the total prediction time ratio.

Accordingly, it is necessary to investigate the characteristics of the emission pattern according to the level of HCHO and determine how much time is needed to obtain an appropriate prediction time through further research.

Conclusions

In this study, when an empirical model is applied based on the emission pattern of HCHO for six building material specimens, the effect of each emission pattern on important division points is identified.

  1. The judgment for selecting the first-order decay model and the double exponential decay model was based on the fact that the HCHO emission pattern had the shape of a vertex. In addition, the linear relationship between emission intensity and time elapsed in the ascending concentration section was more significant. In the concentration descending area, the linear relationship was weakened. Thus, applying the double exponential decay model was appropriate for two or more inflection point graphs. When there is a high linear relationship between emission intensity and time elapse in the concentration ascending section and the concentration descending section, it was confirmed that selecting the first-order reduction model was more appropriate.

  2. Based on the emission pattern of HCHO in building materials, it was classified into three types according to the characteristics of the compatibility between the predicted values and the actual values. In Type I (R2 = .02–.25), the emission of chemical substances reaches the maximum after the start of the experiment and decreases relatively rapidly. Type II (R2 = .67–.70) is an emission pattern with a vertex shape with a slight concentration increase and a gentle decrease. It is a type in which the suitability is significantly high in the concentration descending section. Type III (R2 = .77–.93) is an emission pattern that shows a mild linear increase and decreases trend in the concentration ascending section and the descending concentration area. It is a type that offers the suitability with the predicted value in a meaningful way in the entire section.

  3. Most previous studies decided to apply the first order or double exponential decay model to consider the chemical emission characteristics in the concentration descending section according to the difference in material types. However, this study confirmed that the emission characteristics in the initial concentration ascending section and the concentration descending section are important division points for model selection. This study found that R2, the degree of explanation of the predicted values for the measured values in the concentration descending section, was in the range of .51 to .95 in all cases and showed a good fit. However, the ascending concentration section distinguished the difference between high and low suitability. Therefore, the suitability of the measured values and the predicted values in the emission pattern of the entire area was most affected by the suitability in the concentration ascending period, so the excellent suitability in the concentration ascending section generally showed suitable suitability in the overall emission pattern.

Acknowledgements

The authors would like to express their gratitude to Ajman University for APC support and Healthy and Sustainable Buildings Research Center at Ajman University for providing great research environment.

Author Contributions Chuloh Jung: Writing - Original Draft, Conceptualization, Methodology, Data curation.

Naglaa Sami Abdelaziz Mahmoud: Writing—Review & Editing, Investigation, Project Administration, Resources, Software, Formal analysis, Validation, Supervision.

Author Contributions All authors contributed significantly to this study. C.J. and N.A. identified and secured the example buildings used in the study. The data acquisition system and installation of sensors were designed and installed by C.J. and N.A. N.A. was responsible for data collection. C.J. performed data analysis. The manuscript was compiled by C.J. and reviewed by N.A. All authors have read and agreed to the published version of the manuscript.

Declaration of Conflicting Interests The author(s) declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

Funding The author(s) received no financial support for the research, authorship, and/or publication of this article.

Data Availability Statement New data were created or analyzed in this study. Data will be shared upon request and consideration of the authors.

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© The Author(s) 2022
Chuloh Jung and Naglaa Sami Abdelaziz Mahmoud "Extracting the Critical Points of Formaldehyde (HCHO) Emission Model in Hot Desert Climate," Air, Soil and Water Research 15(1), (24 June 2022). https://doi.org/10.1177/11786221221105082
Published: 24 June 2022
KEYWORDS
double exponential decay
emission pattern
first order decay
Formaldehyde (HCHO)
hot desert climate
important factors
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