Fertility enhancement with biochar application is well documented for tropical acidic soils; however, benefits of biochar coapplied with synthetic fertilizers (SFs) on soil fertility are not well documented, particularly for alkaline chernozems. We examined the short-term interactive effects of woodchip biochar amendment with fertilizers on selected soil properties, available phosphorus (P), and P fractions of two alkaline Chernozems from Manitoba. Treatments were (1) urea and monoammonium phosphate fertilizers, (2) biochar at 10 g kg⁻¹, (3) biochar at 20 g kg⁻¹, (4) biochar at 10 g kg⁻¹ with fertilizers, (5) biochar at 20 g kg⁻¹ with fertilizers, and (6) a control. Treated soils were analysed for pH, electrical conductivity (EC), and Olsen P concentration biweekly, and for P fractions, cation exchange capacity (CEC), organic carbon (OC), and wet aggregate stability after 70 d of incubation. Biochar amendment without fertilizers significantly increased soil pH and CEC but had no effect on EC, while coapplication with fertilizers significantly increased Olsen P and labile P concentrations. When coapplied with fertilizers, biochar did not significantly increase soil pH relative to the control. Results suggest that biochar improved soil properties and available P in alkaline Chernozems, and the beneficial effects were enhanced when coapplied with SFs.